(北京科技大學(xué),腐蝕與防護(hù)中心,北京 100083)
摘要:本文研究了缺陷涂層在不同水質(zhì)的飲用水模擬溶液中的腐蝕機(jī)理,分別采用掃描電子顯微鏡(SEM)和EDS能譜儀對(duì)腐蝕產(chǎn)物的形貌和成分進(jìn)行了分析。結(jié)果表明,在含Ca2+較多的溶液中,缺陷處形成致密的水垢,延緩?fù)繉拥年帢O剝離進(jìn)程,并在水垢附近形成雙層銹結(jié)構(gòu);在含Ca2+較少的溶液中,垢的生長(zhǎng)受到限制,無(wú)法起到保護(hù)作用,缺陷處布滿(mǎn)黃銹,并且起泡現(xiàn)象嚴(yán)重。
關(guān)鍵詞:涂層;腐蝕;飲用水;缺陷;剝離
Effects of the quality of drinking water on the corrosion mechanism of defected coating
YANG Minna,LU Lin,GAO Jin,LI Xiaogang
Corrosion and Protection Center,University of Science and Technology Beijing,Beijing 100083
Abstract:The corrosion mechanism of defected coating were studied in synthetic drinking water with different composition. The morphology and composition of corrosion products were characterized by Scanning Electron Microscope (SEM) and Energy Dispersive Spectrometer (EDS)。 The results show that the sample immersing in the solution containing more Ca2+ were protected by scale deposit covering the defect, which delayed the process of cathodic delamination. In the solution containing less Ca2+, the coating blistered around the defect because of the loose accumulation of the corrosion products.
Key Words:coating,corrosion,drinking water,defect,delamination
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